Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(?-quinolin-8-olato)-?N,O:O;?O:N,O-bis-[chloridomethyl-phenyl-tin(IV)].

ABSTRACT: The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83?(8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H?Cl hydrogen bonding links the mol-ecules, forming supra-molecular chains running along [100].

SUBMITTER: Vafaee M

PROVIDER: S-EPMC3007587 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(μ-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[chloridomethyl-phenyl-tin(IV)].

Vafaee Maryam M Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonding links the mol-ecules, forming supra-molecular chains running along [100]. ...[more]

PMID: 21588189

Similar Datasets

Bis(isopropoxido-κO)bis-(2-methyl-quinolin-8-olato-κN,O)titanium(IV).

Project description:The two 2-methyl-quinolin-8-olate anions in the title complex, [Ti(C(10)H(8)NO)(2)(C(3)H(7)O)(2)], chelate the Ti(IV) atom, which shows an all-cis distorted octa-hedral N(2)O(4) coordination geometry.

| S-EPMC2960138 | biostudies-literature

Bis(μ-2-methyl-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[(acetato-κO)(methanol-κO)zinc(II)].

Project description:The reaction of zinc acetate and 2-methyl-8-hydroxy-quinoline in methanol yielded the centrosymmetric dinuclear title compound, [Zn(2)(C(10)H(8)NO)(2)(CH(3)CO(2))(2)(CH(3)OH)(2)], which has the Zn atom within a distorted NO(4) trigonal-bipyramidal coordination geometry. Methanol-acetate O-H⋯O hydrogen bonds link the dinculear units into a linear supra-molecular chain extending parallel to [100].

| S-EPMC2977601 | biostudies-literature

Chloridometh-yl(2-methyl-quinolin-8-olato-?N,O)phenyl-tin(IV).

Project description:The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82?(8) and 137.69?(8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Sn?Cl distance of 3.595?(1)?Å. Weak inter-molecular C-H?O and C-H?Cl hydrogen bonding is present in the crystal structure.

| S-EPMC3007514 | biostudies-literature

Dimethyl-bis-(2-methyl-quinolin-8-olato-?(2) N,O)tin(IV).

Project description:The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91?(18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6?(2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter-molecular C-H?O hydrogen bonding occurs in the crystal.

| S-EPMC3588791 | biostudies-literature

Benzyl-chloridobis(quinolin-8-olato)tin(IV).

Project description:In the title compound, [Sn(C(7)H(7))(C(9)H(6)NO)(2)Cl], the Sn(IV) ion is in a distorted octa-hedral coordination environment formed by the O and N atoms of two bis-chelating quinolin-8-olate ligands, a Cl atom and a C atom from a benzyl ligand. The axial sites are occupied by an N atom of a quinolinate ligand and the C atom of the benzyl ligand. The axial Sn-N bond is slightly shorter than the equatorial Sn-N bond.

| S-EPMC2977110 | biostudies-literature

Di-μ(3)-oxido-bis-(μ(2)-quinaldato-κO:O)-bis-(quinaldato-κN,O)tetra-kis[di-n-butyl-tin(IV)].

Project description:The title tetra-nuclear Sn(IV) complex, [Sn(4)(C(4)H(9))(8)(C(10)H(6)NO(2))(4)O(2)], is a cluster built up by inversion symmetry around the central Sn(2)O(2) ring. The coordination geometries of the Sn atoms involved can be classified into two types: the five-coordinate Sn atoms of the central Sn(2)O(2) core have a trigonal-bipyramidal geometry, with axial positions occupied by a μ(3)-O atom and a μ(2)-O atom belonging to the nonchelating quinaldate ligand. The peripheral Sn atoms are six-coordinate, with a distorted octa-hedral geometry. The methyl group of an n-butyl ligand is disordered over two sites, with occupancies of 0.643 (12) and 0.357 (12).

| S-EPMC2915128 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

| S-EPMC3051585 | biostudies-literature

Bis(μ-chloroacetato-κO:O')bis(chloro-acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl-tin(IV)].

Project description:The title tetra-nuclear complex mol-ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal-bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C-H⋯O hydrogen bonds. In the crystal, complex mol-ecules are linked into zigzag chains along [110] by C-H⋯O hydrogen bonds.

| S-EPMC3051761 | biostudies-literature

Di-μ-methanolato-κO:O-bis[tri-chlorido(dimethyl-formamide-κO)tin(IV)].

Project description:The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa-coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa-hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl-formamide mol-ecule. The complex mol-ecules are connected by weak C-H⋯Cl hydrogen bonds into a two-dimensional supra-molecular network parallel to (10).

| S-EPMC3051740 | biostudies-literature

(Methoxo-κO)oxidobis(quinolin-8-olato-κN,O)vanadium(V).

Project description:In the title complex, [V(C(9)H(6)NO)(2)(CH(3)O)O], the central V(V) atom is coordinated by the O atoms from the oxido and methoxo ligands and the N and O atoms of two bis-chelating quinolin-8-olate ligands, forming a distorted octa-hedral environment. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds connect mol-ecules into centrosymmetric dimers which are, in turn, linked by weak C-H⋯π inter-actions into chains along the b axis.

| S-EPMC2969990 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data