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Bis(?-quinolin-8-olato)-?N,O:O;?O:N,O-bis-[chloridomethyl-phenyl-tin(IV)].

ABSTRACT: The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83?(8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H?Cl hydrogen bonding links the mol-ecules, forming supra-molecular chains running along [100].

SUBMITTER: Vafaee M 

PROVIDER: S-EPMC3007587 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bis(μ-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[chloridomethyl-phenyl-tin(IV)].

Vafaee Maryam M   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

The Sn(IV) atom in the centrosymmetric dinculear title compound, [Sn(2)(CH(3))(2)(C(6)H(5))(2)(C(9)H(6)NO)(2)Cl(2)], shows a trans-C(2)SnNO(2)Cl distorted octa-hedral coordination [C-Sn-C = 157.83 (8)°]. The quinolin-8-olate anion chelates to the Sn atom; its O atom also binds to the inversion-related Sn atom, forming the dinuclear compound. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonding links the mol-ecules, forming supra-molecular chains running along [100]. ...[more]

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