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2-Fluoro-4-(meth-oxy-carbon-yl)benzoic acid.

ABSTRACT: In the crystal of the title compound, C(9)H(7)FO(4), classical carboxylate inversion dimers are linked by pairs of O-H?O hydrogen bonds. The packing is consolidated by C-H?F and C-H?O interactions. The benzene ring and the methoxycarbonyl group are nearly coplanar, with a dihedral angle of 1.5?(3)° between them, whereas the carboxyl group has a dihedral angle of 20.2?(4)° with respect to the benzene ring.

SUBMITTER: Wagner CE

PROVIDER: S-EPMC3008027 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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2-Fluoro-4-(meth-oxy-carbon-yl)benzoic acid.

Wagner Carl E CE Groy Thomas L TL

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9

In the crystal of the title compound, C(9)H(7)FO(4), classical carboxylate inversion dimers are linked by pairs of O-H⋯O hydrogen bonds. The packing is consolidated by C-H⋯F and C-H⋯O interactions. The benzene ring and the methoxycarbonyl group are nearly coplanar, with a dihedral angle of 1.5 (3)° between them, whereas the carboxyl group has a dihedral angle of 20.2 (4)° with respect to the benzene ring. ...[more]

PMID: 21588685

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