Unknown

Dataset Information

0

[2-(Diphenyl-phosphan-yl)benzene-thiol-ato-?P,S](pyridine-2-thiol-ato-?S)(triphenyl-phosphine-?P)palladium(II).

ABSTRACT: In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H?? and ?-? inter-actions are observed. The pyridyl ring is equally disordered over two positions.

SUBMITTER: Rios-Sanchez R 

PROVIDER: S-EPMC3008042 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

[2-(Diphenyl-phosphan-yl)benzene-thiol-ato-κP,S](pyridine-2-thiol-ato-κS)(triphenyl-phosphine-κP)palladium(II).

Ríos-Sanchez Raúl R   Hernández-Ortega Simón S   Morales-Morales David D   Avila-Sorrosa Alcives A  

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H⋯π and π-π inter-actions are  ...[more]

Similar Datasets

Unknown Chlorido(ethyl-diphenyl-phosphine-κP)(1-pyrrolidinecarbodithio-ato-κS,S')nickel(II).
| S-EPMC2961319 | biostudies-literature
Unknown trans-Chlorido-(4-fluoro-benzene-thiol-ato-κS)bis-(tri-phenyl-phosphane-κP)palladium(II) methanol hemisolvate.
| S-EPMC3998499 | biostudies-literature
Unknown Bis(methyl xanthato)-κS;κS:S'-(triphenyl-phosphane-κP)palladium(II).
| S-EPMC3246946 | biostudies-literature
Unknown (Triphenyl-phosphine-κP)[1,1,1-tris-(diphenyl-phosphinometh-yl)ethane-κP,P',P'']copper(I) tetra-fluoridoborate.
| S-EPMC2983927 | biostudies-literature
Unknown [(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).
| S-EPMC2971922 | biostudies-literature
Unknown (Dithio-benzoato-κS,S')[hydridotris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II).
| S-EPMC2960112 | biostudies-literature
Unknown Bis(carbonyl-κC)(N,N-dimethyl-thio-carbamoyl-κC,S)(pyridine-2-thiol-ato-κN,S)(triphenyl-phosphine-κP)molybdenum(II).
| S-EPMC2983129 | biostudies-literature
Unknown [(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).
| S-EPMC2971960 | biostudies-literature
Unknown [(Z)-O-Isopropyl N-phenyl-thio-car-bam-ato-κS](tricyclo-hexyl-phosphine-κP)gold(I).
| S-EPMC2983967 | biostudies-literature
Unknown (O,O'-Diethyl dithio-phosphato-κS,S')(hydridotripyrazol-1-ylborato-κN,N,N)(triphenyl-phosphine-κP)ruthenium(II).
| S-EPMC2959604 | biostudies-literature