Browse
Submit Data
Databases
API
Help

Dataset Information

22 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[2-(Diphenyl-phosphan-yl)benzene-thiol-ato-?P,S](pyridine-2-thiol-ato-?S)(triphenyl-phosphine-?P)palladium(II).

ABSTRACT: In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H?? and ?-? inter-actions are observed. The pyridyl ring is equally disordered over two positions.

SUBMITTER: Rios-Sanchez R

PROVIDER: S-EPMC3008042 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[2-(Diphenyl-phosphan-yl)benzene-thiol-ato-κP,S](pyridine-2-thiol-ato-κS)(triphenyl-phosphine-κP)palladium(II).

Ríos-Sanchez Raúl R Hernández-Ortega Simón S Morales-Morales David D Avila-Sorrosa Alcives A

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H⋯π and π-π inter-actions are ...[more]

PMID: 21588560

Similar Datasets

trans-Chlorido-(4-fluoro-benzene-thiol-ato-κS)bis-(tri-phenyl-phosphane-κP)palladium(II) methanol hemisolvate.

Project description:The title compound, [Pd(SC6H4F-p)Cl(PPh3)2]·0.5CH3OH, features a Pd(II) complex with two tri-phenyl-phosphane (PPh3) ligands arranged in a trans conformation, with one chloride and one 4-fluoro-benzene-thiol-ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd(II) ion. The methanol solvent mol-ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C-H⋯Cl hydrogen-bonding inter-actions between the complex mol-ecules generate chain frameworks parallel to [010].

| S-EPMC3998499 | biostudies-literature

Bis(methyl xanthato)-κS;κS:S'-(triphenyl-phosphane-κP)palladium(II).

Project description:The title compound, [Pd(C(2)H(3)OS(2))(2)(C(18)H(15)P)], features a palladium complex with a triphenyl-phosphane ligand and two xanthate ligands, one of them coordinates in a bidentate and the other in a monodentate fashion, giving rise to a slightly distorted square-planar coordination of the Pd(II) ion. As a result of this difference in the coordination modes, the C-S bond lengths are different, viz. 1.687 (2) and 1.692 (2) Å in the bidentate ligand and 1.723 (2) Å in the monodentate ligand, whereas the non-coordinating S atom has a C-S distance of 1.649 (2) Å. The crystal packing is stabilized by C-H⋯O inter-actions.

| S-EPMC3246946 | biostudies-literature

(Triphenyl-phosphine-κP)[1,1,1-tris-(diphenyl-phosphinometh-yl)ethane-κP,P',P'']copper(I) tetra-fluoridoborate.

Project description:In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra-hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two positions, with an occupancy ratio of 0.524 (17):0.476 (17). The cations and anions are closely packed in the crystal and are in h.c.p. arrangements.

| S-EPMC2983927 | biostudies-literature

[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å].

| S-EPMC2971922 | biostudies-literature

(Dithio-benzoato-κS,S')[hydridotris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II).

Project description:Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru-S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N-Ru-N angle is 86.31°.

| S-EPMC2960112 | biostudies-literature

[(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].

| S-EPMC2971960 | biostudies-literature

[(Z)-O-Isopropyl N-phenyl-thio-car-bam-ato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions.

| S-EPMC2983967 | biostudies-literature

[O-Ethyl N-(4-nitro-phen-yl)thio-carbam-ato-κS](tri-p-tolyl-phosphine-κP)gold(I).

Project description:A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].

| S-EPMC2959883 | biostudies-literature

rac-Carbon-yl{1-[(diphenyl-phosphino)meth-yl]ethanethiol-ato}(triphenyl-phosphine)rhodium(I).

Project description:The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P-S ligand [Ph(2)PCH(2)CH(CH(3))S] acting as a chelate and the PPh(3) and disordered CO [site occupation factors of 0.61?(5) and 0.39?(5)] ligands completing the coordination.

| S-EPMC2959607 | biostudies-literature

Azido-(1,1-diphenyl-methanimine-κN)[hydridotris(pyrazolyl-κN)borato](triphenyl-phosphine-κP)ruthenium(II) diethyl ether solvate.

Project description:The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru-N-N angle of 125.9 (3)°. There is a small difference between the N-N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

| S-EPMC2960095 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data