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2-Cyano-quinolin-1-ium hydrogen sulfate.

ABSTRACT: The title salt, C(10)H(7)N(2) (+)·HSO(4) (-), is formed by the transfer of a proton from H(2)SO(4) to the N atom of 2-cyano-quinoline during crystallization. The quinoline ring system is approximately planar with a maximum deviation of 0.013?(3)?Å. In the crystal, the cations are linked to the anions via inter-molecular N-H?O, O-H?O and C-H?O hydrogen bonds, forming a layered network.

SUBMITTER: Loh WS

PROVIDER: S-EPMC3009120 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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2-Cyano-quinolin-1-ium hydrogen sulfate.

Loh Wan-Sin WS Hemamalini Madhukar M Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20101002 Pt 11

The title salt, C(10)H(7)N(2) (+)·HSO(4) (-), is formed by the transfer of a proton from H(2)SO(4) to the N atom of 2-cyano-quinoline during crystallization. The quinoline ring system is approximately planar with a maximum deviation of 0.013 (3) Å. In the crystal, the cations are linked to the anions via inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds, forming a layered network. ...[more]

PMID: 21588923

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