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Hexaaqua-nickel(II) 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate monohydrate.

ABSTRACT: In the title compound, [Ni(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, the Ni(II) cation is located on a mirror plane and is coordinated by six water mol-ecules, two of which are also located on the mirror plane, in a distorted octa-hedral geometry. The 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate anion is centrosymmetric with the mid-point of the central ethane C-C bond located on an inversion center. The uncoordinated water mol-ecule is located on a mirror plane. Extensive O-H?O hydrogen bonding is present in the crystal structure.

SUBMITTER: Li SJ

PROVIDER: S-EPMC3009210 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Hexaaqua-nickel(II) 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate monohydrate.

Li Shi-Jie SJ Hu Shi-Wei SW Song Wen-Dong WD Qin Pei-Wen PW Ma Xiao-Tian XT

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

In the title compound, [Ni(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, the Ni(II) cation is located on a mirror plane and is coordinated by six water mol-ecules, two of which are also located on the mirror plane, in a distorted octa-hedral geometry. The 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate anion is centrosymmetric with the mid-point of the central ethane C-C bond located on an inversion center. The uncoordinated water mol-ecule is located on a mirror plane. Extensive O-H⋯O hydrogen bonding is ...[more]

PMID: 21588821

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