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2,2'-Biimidazolium 5-amino-2,4,6-tri-bromo-isophthalate.


ABSTRACT: In the cation of the title salt, C(6)H(8)N(4) (2+)·C(8)H(2)Br(3)NO(4) (2-), the dihedral angle between the two five-membered rings is 2.1?(3)°. In the anion, the mean planes of the carboxyl units are twisted from the benzene ring by 84.3?(4) and 86.2?(3)°. In the crystal, the components are linked by imidazolium-carboxyl-ate N-H?O hydrogen bonds, generating a chain running along [10].

SUBMITTER: Zhang KL 

PROVIDER: S-EPMC3009234 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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2,2'-Biimidazolium 5-amino-2,4,6-tri-bromo-isophthalate.

Zhang Kou-Lin KL   Huang Han H   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11


In the cation of the title salt, C(6)H(8)N(4) (2+)·C(8)H(2)Br(3)NO(4) (2-), the dihedral angle between the two five-membered rings is 2.1 (3)°. In the anion, the mean planes of the carboxyl units are twisted from the benzene ring by 84.3 (4) and 86.2 (3)°. In the crystal, the components are linked by imidazolium-carboxyl-ate N-H⋯O hydrogen bonds, generating a chain running along [10]. ...[more]

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