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4-Phenyl-sulfon-yl-2-(p-tolyl-sulfon-yl)-1H,8H-pyrrolo-[2,3-b]indole.

ABSTRACT: The title compound, C(23)H(18)N(2)O(4)S(2), contains a pyrrolo group fused onto the plane of an indole ring with phenyl-sulfonyl and p-toluene-sulfonyl groups bonded to the indole and pyrrolo rings. The angles between the mean planes of the pyrrolo-indole ring and the phenyl-sulfonyl and p-toluene-sulfonyl rings are 73.7?(6) and 80.6?(0)°, respectively. The dihedral angle between the mean planes of the two benzene rings is 78.7?(4)°. In the crystal, both classical N-H?O and non-classical C-H?O inter-molecular hydrogen-bonding inter-actions are observed, as well as weak ?-? inter-actions [centroid-centroid distances = 3.6258?(8) and 3.9298?(8)?Å], which contribute to the stability of the packing.

SUBMITTER: Badenock JC 

PROVIDER: S-EPMC3009299 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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4-Phenyl-sulfon-yl-2-(p-tolyl-sulfon-yl)-1H,8H-pyrrolo-[2,3-b]indole.

Badenock Jeanese C JC   Jordan Jason A JA   Pelkey Erin T ET   Gribble Gordon W GW   Jasinski Jerry P JP  

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

The title compound, C(23)H(18)N(2)O(4)S(2), contains a pyrrolo group fused onto the plane of an indole ring with phenyl-sulfonyl and p-toluene-sulfonyl groups bonded to the indole and pyrrolo rings. The angles between the mean planes of the pyrrolo-indole ring and the phenyl-sulfonyl and p-toluene-sulfonyl rings are 73.7 (6) and 80.6 (0)°, respectively. The dihedral angle between the mean planes of the two benzene rings is 78.7 (4)°. In the crystal, both classical N-H⋯O and non-classical C-H⋯O i  ...[more]

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