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Iodidobis(?-penta-methyl-cyclo-penta-dien-yl)titanium(III).

ABSTRACT: In the title complex mol-ecule, [Ti(C(10)H(15))(2)I], the paramagnetic Ti(III) atom is coordinated by two penta-methyl-cyclo-penta-dienyl (Cp*) ligands and one iodide ligand. The two Cp* ligands are in a staggered orientation. The coordination geometry at the titanium atom can be described as distorted trigonal-planar.

SUBMITTER: Kessler M

PROVIDER: S-EPMC3009319 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Iodidobis(η-penta-methyl-cyclo-penta-dien-yl)titanium(III).

Kessler Monty M Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20101013 Pt 11

In the title complex mol-ecule, [Ti(C(10)H(15))(2)I], the paramagnetic Ti(III) atom is coordinated by two penta-methyl-cyclo-penta-dienyl (Cp*) ligands and one iodide ligand. The two Cp* ligands are in a staggered orientation. The coordination geometry at the titanium atom can be described as distorted trigonal-planar. ...[more]

PMID: 21588833

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