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Catena-Poly[[(1,10-phenanthroline-?N,N')copper(I)]-?(2)-iodido].

ABSTRACT: The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(-) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are bridged through the iodide anions, leading to a zigzag chain structure extending parallel to [100]. There are ?-? inter-actions among adjacent phen ligands of one chain [centroid-centroid distance = 3.693?(3)?Å].

SUBMITTER: Yang Y

PROVIDER: S-EPMC3009332 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[(1,10-phenanthroline-κN,N')copper(I)]-μ(2)-iodido].

Yang Yisheng Y Chai Wenxiang W Song Li L Shu Kangying K

Acta crystallographica. Section E, Structure reports online 20101031 Pt 11

The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(-) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are bridged through the iodide anions, leading to a zigzag chain structure extending parallel to [100]. Ther ...[more]

PMID: 21588901

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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato].

Project description:In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa-hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu-phen units in zigzag chains extending parallel to [100]. Inter-chain C-H⋯O hydrogen bonding and π-π stacking inter-actions [centroid-centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supra-molecular network.

| S-EPMC2983185 | biostudies-literature

catena-Poly[[[(1,10-phenanthroline)copper(I)]-?-cyanido] ethanol hemisolvate].

Project description:In the title coordination polymer, {[Cu(CN)(C(12)H(10)N(2))]·0.5C(2)H(5)OH}(n), there are two Cu(I) ions, two 1,10-phenanthroline (phen) ligands and two cyanide ions in the asymmetric unit along with a highly disordered ethanol solvent mol-ecule, which was modelled as being disordered over two sets of sites in a 0.829?(7):0.171?(7) ratio. The orientation/ordering of the C and N atoms of the cyanide ions could not be determined in the present refinement and they were modelled as being statistically disordered. Both copper ions are coordinated by an N,N'-bidentate phen ligand and two cyanide ligands, generating distorted tetra-hedral CuN(2)Q(2) (Q = C or N) tetra-hedra. The ?-cyanide ligands link the metal ions, forming a zigzag chain propagating in [001]. The chains are cross-linked by numerous aromatic ?-? stacking contacts between adjacent phen rings [minimum centroid-centroid separation = 3.620?(3)?Å].

| S-EPMC3011795 | biostudies-literature

catena-Poly[[(1,10-phenanthroline-κN,N')copper(I)]-μ-thiocyanato-κN:S-[(1,10-phenanthroline-κN,N')copper(I)]-μ-cyanido-κN:C].

Project description:In the title complex, [Cu(2)(CN)(NCS)(C(12)H(8)N(2))(2)], which was synthesized under hydro-thermal conditions, both Cu(I) atoms have a slightly distorted tetra-hedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thio-cyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along [01].

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catena-Poly[[(1,10-phenanthroline)cobalt]-?-2,4'-oxydibenzoato].

Project description:In the title compound, [Co(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Co(II) atom is six-coordinated in a distorted octa-hedral coordination geometry by four O atoms from two chelating carboxyl-ate groups from different 2,4'-oxydibenzoate anions and by two N atoms from a 1,10-phenanthroline (phen) ligand. The two benzene rings of the 2,4'-oxydibenzoate ligand form a dihedral angle of 77.14?(16)°. Adjacent Co(II) atoms are bridged by 2,4'-oxydibenzoate anions to form a helical chain that propagates along the b-axis direction. Neighboring chains are further assembled by inter-molecular ?-? stacking inter-actions between inversion-related phen ligands [centroid-to-centroid distance = 4.0869?(8)?Å] to form a two-dimensional supra-molecular architecture.

| S-EPMC3414136 | biostudies-literature

catena-Poly[[(1,10-phenanthroline-κN,N')copper(I)]-μ-thio-cyanato-κN:S].

Project description:In the title complex, [Cu(NCS)(C(12)H(8)N(2))](n), the Cu(I) ion is in a distorted tetra-hedral CuN(3)S coordination geometry. The thio-cyanate ligand acts as bridging ligand, forming chains along [100]. A crystallographic mirror plane runs through the Cu(I) ion, the thio-cyanate ligand and the middle of the phenanthroline ligand.

| S-EPMC2983214 | biostudies-literature

Iodido(1,10-phenanthroline-?N,N')(piperine-1-carbodithioato-?S,S')copper(II).

Project description:In the title compound, [Cu(C(6)H(10)NS(2))I(C(12)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the phenanthroline ligand and two S atoms from the piperidyl-dithio-carbamate ligand in a distorted square-pyramidal environment.

| S-EPMC2959432 | biostudies-literature

catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl-isophthalato].

Project description:In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn-N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn-O = 2.112 (2)-2.343 (3) Å] from three 5-methyl-isophthalate (mip) ligands in a distorted octa-hedral geometry. Each mip dianion acts as a tetra-dentate ligand connecting three Mn ions. The crystal packing exhibits π-π inter-actions [3.599 (2)-3.755 (2) Å] between the centroids of the six-membered rings of neighbouring 1,10-phenanthroline ligands.

| S-EPMC2960010 | biostudies-literature

catena-Poly[[(1,10-phenanthroline)zinc]-?-2,2'-oxydibenzoato].

Project description:In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octa-hedral coordination geometry with four O atoms from two carboxyl-ate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal carboxyl-ate groups bind the Zn(II) ions, leading to a chain along the c axis. Adjacent chains are further linked by inter-molecular ?-? inter-actions with a shortest centroid-centroid distance of 3.586?(3)?Å, forming a two-dimensional supra-molecular architecture with (6,3)-network topology.

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catena-Poly[[(pyrazine-2-carboxamide-?N (4))copper(I)]-?3-iodido].

Project description:In the title metal-organic polymeric complex, [CuI(C5H5N3O)] n , the asymmetric unit is composed of one monomer unit of the polymer and one Cu(I) atom linked to one iodide anion and one pyrazine-2-carboxamide mol-ecule. The Cu(I) atom is in a distorted tetra-hedral coordination completed by one pyrazine N atom of the pyrazine-2-carboxamide ligand and three iodide anions. The polymeric structure adopts a well-known ladder-like motif of {CuNI3} tetra-hedra running in the b-axis direction. The mol-ecules of the organic ligand are connected via medium-to-strong N-H?O and N-H?N hydrogen bonds and weak ?-? inter-actions [the distance between two parallel planes of the rings is 3.5476?(14)?Å and the centroid-centroid contact is 4.080?(2)?Å]. The title compound has a relatively high decomposition temperature (564?K) as a result of relatively strong covalent and non-covalent inter-actions inside and between the chains.

| S-EPMC4120587 | biostudies-literature

catena-Poly[[(1,10-phenanthroline)cobalt(II)]-di-?-azido].

Project description:In the crystal structure of the binuclear title complex, [Co(N(3))(2)(C(12)H(8)N(2))](n), each Co(II) cation is coordinated by two N atoms from one chelating 1,10-phenanthroline ligand and four azide ligands in a slightly distorted octa-hedral coordination. The two Co(II) cations of the binuclear complex are related by an inversion centre and are bridged by two symmetry-related azide ligands in both ?(1,1) and ?(1,3) modes. The ?(1,3) bridging mode gives rise to an infinite one-dimensional chain along the a axis, whereas the ?(1,1) bridging mode is responsible for the formation of the binuclear Co(II) complex.

| S-EPMC3297267 | biostudies-other

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