Unknown

Dataset Information

0

A light controlled cavitand wall regulates guest binding.


ABSTRACT: Here we report a cavitand with a photochemical switch as one of the container walls. The azo-arene switch undergoes photoisomerization when subjected to UV light producing a self-fulfilled cavitand. This process is thermally and photochemically reversible. The reported cavitand binds small molecules and these guests can be ejected from the cavitand through this photochemical process.

SUBMITTER: Berryman OB 

PROVIDER: S-EPMC3010387 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

altmetric image

Publications

A light controlled cavitand wall regulates guest binding.

Berryman Orion B OB   Sather Aaron C AC   Rebek Julius J  

Chemical communications (Cambridge, England) 20101129 2


Here we report a cavitand with a photochemical switch as one of the container walls. The azo-arene switch undergoes photoisomerization when subjected to UV light producing a self-fulfilled cavitand. This process is thermally and photochemically reversible. The reported cavitand binds small molecules and these guests can be ejected from the cavitand through this photochemical process. ...[more]

Similar Datasets

| S-EPMC2966534 | biostudies-literature
| S-EPMC5890788 | biostudies-literature
| S-EPMC3186209 | biostudies-literature
| S-EPMC6362660 | biostudies-literature
| S-EPMC6399691 | biostudies-literature
| S-EPMC9864885 | biostudies-literature
| S-EPMC6456573 | biostudies-literature
| S-EPMC10831044 | biostudies-literature
| S-EPMC4311808 | biostudies-other
| S-EPMC7442968 | biostudies-literature