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Bromido(dodecafluorosubphthalo-cyaninato)boron(III).

ABSTRACT: The title compound, C(24)BBrF(12)N(6) or Br-F(12)BsubPc (BsubPc is boronsubphtalocyanine), has a bowl-shaped structure with an approximate mol-ecular C(3v) symmetry characteristic of boronsubphthalocyanine compounds. In the crystal, mol-ecules are arranged in one-dimensional columns and the boron-subphthalocyanine units within each column are offset and angled in a bowl-to-ligand packing arrangement such that the axial Br atom rests in the aromatic concaved bowl of the neighboring subphthalocyanine with an inter-molecular Br?B distance of 3.721?(3)?Å.

SUBMITTER: Morse GE

PROVIDER: S-EPMC3011383 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bromido(dodecafluorosubphthalo-cyaninato)boron(III).

Morse Graham E GE Maka Jozef F JF Lough Alan J AJ Bender Timothy P TP

Acta crystallographica. Section E, Structure reports online 20101106 Pt 12

The title compound, C(24)BBrF(12)N(6) or Br-F(12)BsubPc (BsubPc is boronsubphtalocyanine), has a bowl-shaped structure with an approximate mol-ecular C(3v) symmetry characteristic of boronsubphthalocyanine compounds. In the crystal, mol-ecules are arranged in one-dimensional columns and the boron-subphthalocyanine units within each column are offset and angled in a bowl-to-ligand packing arrangement such that the axial Br atom rests in the aromatic concaved bowl of the neighboring subphthalocyan ...[more]

PMID: 21589368

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