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Catena-Poly[[[diaqua-(nitrato-?O,O')cerium(III)]-bis-[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'] mono-hydrate].


ABSTRACT: In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water mol-ecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, inter-molecular O-H?O hydrogen bonds form a three-dimensional network which consolidates the packing.

SUBMITTER: Guo HM 

PROVIDER: S-EPMC3011495 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[[diaqua-(nitrato-κO,O')cerium(III)]-bis-[μ-2-(4-hy-droxy-phen-yl)acetato]-κO,O':O;κO:O,O'] mono-hydrate].

Guo Hang-Ming HM  

Acta crystallographica. Section E, Structure reports online 20101120 Pt 12


In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water mol-ecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, inter-molecular O-H⋯O hydrogen bonds form a three-dimensional network which consolidates the packing. ...[more]

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