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N-[(E)-1,3-Benzodioxol-5-yl-methyl-idene]-4-methyl-aniline.

ABSTRACT: The two symmetry-independent mol-ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl-aniline (r.m.s. deviations of 0.0511 and 0.0082?Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486?Å) forming dihedral angles of 19.40?(5) and 42.90?(6)°. In the crystal, mol-ecules are linked by C-H?O and C-H?? inter-actions. The H atoms of the two methyl groups are disordered over two sets of sites of equal occupancy.

SUBMITTER: Tahir MN 

PROVIDER: S-EPMC3011519 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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N-[(E)-1,3-Benzodioxol-5-yl-methyl-idene]-4-methyl-aniline.

Tahir M Nawaz MN   Shad Hazoor Ahmad HA   Khan Muhammad Naeem MN   Tariq Riaz H RH  

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

The two symmetry-independent mol-ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl-aniline (r.m.s. deviations of 0.0511 and 0.0082 Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486 Å) forming dihedral angles of 19.40 (5) and 42.90 (6)°. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯π inter-actions. The H atoms of the two methyl groups are disordered over two sets of sites of equal occupancy. ...[more]

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