Unknown

Dataset Information

0

(4-tert-Butyl-pyridine)-chlorido[hydro-tris-(3,5-dimethyl-pyrazol-1-yl)borato]nitro-sylmolybdenum(I) dichloro-methane monosolvate.


ABSTRACT: In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa-hedral geometry with the hydro-tris-(3,5-dimethyl-pyrazol-yl)borate anion in an N,N',N''-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intra-molecular C-H?Cl hydrogen bond helps to stabilize the configuration of the complex mol-ecule. The packing is stabilized by an inter-molecular C-H?Cl hydrogen bond involving the complex mol-ecule and the CH(2)Cl(2) solvent mol-ecule.

SUBMITTER: Kassim MB 

PROVIDER: S-EPMC3011577 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

altmetric image

Publications

(4-tert-Butyl-pyridine)-chlorido[hydro-tris-(3,5-dimethyl-pyrazol-1-yl)borato]nitro-sylmolybdenum(I) dichloro-methane monosolvate.

Kassim Mohammad B MB   McCleverty Jon A JA  

Acta crystallographica. Section E, Structure reports online 20101130 Pt 12


In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa-hedral geometry with the hydro-tris-(3,5-dimethyl-pyrazol-yl)borate anion in an N,N',N''-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intra-molecular C-H⋯Cl hydrogen bond helps to stabilize the configuration of the complex mol-ecule. The packing is stabil  ...[more]

Similar Datasets

| S-EPMC3629499 | biostudies-literature
| S-EPMC3099946 | biostudies-literature
| S-EPMC2969450 | biostudies-literature
| S-EPMC3051926 | biostudies-literature
| S-EPMC3647789 | biostudies-literature
| S-EPMC3011797 | biostudies-other
| S-EPMC3414966 | biostudies-literature
| S-EPMC3212124 | biostudies-literature
| S-EPMC3588800 | biostudies-other
| S-EPMC3588519 | biostudies-literature