Ontology highlight
ABSTRACT:
SUBMITTER: Kassim MB
PROVIDER: S-EPMC3011577 | biostudies-literature | 2010 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20101130 Pt 12
In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa-hedral geometry with the hydro-tris-(3,5-dimethyl-pyrazol-yl)borate anion in an N,N',N''-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intra-molecular C-H⋯Cl hydrogen bond helps to stabilize the configuration of the complex mol-ecule. The packing is stabil ...[more]