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Pyridine-2-carboximidamidate chloride monohydrate.

ABSTRACT: The title compound, C(6)H(8)N(3) (+)·Cl(-)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the -C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N-H?N hydrogen bonds, to chloride ions by N-H?Cl hydrogen bonds, and to water mol-ecules by N-H?O hydrogen bonds. Water mol-ecules and chloride ions are also linked together via O-H?Cl hydrogen bonds. In the crystal, all these inter-molecular inter-actions result in a three-dimensional network.

SUBMITTER: Chen Q

PROVIDER: S-EPMC3011583 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Pyridine-2-carboximidamidate chloride monohydrate.

Chen Qifan Q Zhang Huidong H Zhang Fang F Liu Fei F

Acta crystallographica. Section E, Structure reports online 20101113 Pt 12

The title compound, C(6)H(8)N(3) (+)·Cl(-)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the -C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N-H⋯N hydrogen bonds, to chloride ions by N-H⋯Cl hydrogen bonds, and to water mol-ecules by N-H⋯O hydrogen bonds. Water mol-ecules and chloride ions are also linked together via O-H⋯Cl hydrogen bonds. In the crystal, all thes ...[more]

PMID: 21589465

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