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Chlorido(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine)-platinum(II) tetra-fluorido-borate.

ABSTRACT: In the title compound, [PtCl(C(27)H(35)N(3))]BF(4), the Pt(II) atom is in a pseudo-square-planar coordination, which is typical of Pt-terpyridine complexes. The Pt-Cl bond distance is 2.2998?(7)?Å. The Pt-N distance of the N atom on the central pyridine is 1.931?(2)?Å, while the peripheral N atoms have Pt-N distances of 2.018?(2) and 2.022?(2)?Å. The cations pack as dimers in a head-to-tail orientation with an inter-molecular Pt?Pt distance of 3.5214?(2)?Å and Pt?N distances of 3.527?(2), 3.873?(2) and 4.532?(2)?Å. In the crystal, cations and anions are linked by weak C-H?F hydrogen-bonding inter-actions.

SUBMITTER: Batrice RJ

PROVIDER: S-EPMC3011620 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Chlorido(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine)-platinum(II) tetra-fluorido-borate.

Batrice Rami J RJ Nesterov Vladimir N VN Smucker Bradley W BW

Acta crystallographica. Section E, Structure reports online 20101130 Pt 12

In the title compound, [PtCl(C(27)H(35)N(3))]BF(4), the Pt(II) atom is in a pseudo-square-planar coordination, which is typical of Pt-terpyridine complexes. The Pt-Cl bond distance is 2.2998 (7) Å. The Pt-N distance of the N atom on the central pyridine is 1.931 (2) Å, while the peripheral N atoms have Pt-N distances of 2.018 (2) and 2.022 (2) Å. The cations pack as dimers in a head-to-tail orientation with an inter-molecular Pt⋯Pt distance of 3.5214 (2) Å and Pt⋯N distances of 3.527 (2), 3.873 ...[more]

PMID: 21589353

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