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2-Amino-pyridinium 1-phenyl-cyclo-propane-1-carboxyl-ate.

ABSTRACT: In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (-), 2-amino-pyridine and 1-phenyl-cyclo-propane-1-carb-oxy-lic acid crystallize together, forming a 2-amino-pyridinium-carboxyl-ate supra-molecular heterosynthon involving two N-H?O hydrogen bonds, which in turn dimerizes to form a four-component supra-molecular unit also sustained by N-H?O hydrogen bonding. A C-H?? inter-action between a pyridine C-H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supra-molecular unit. The overall crystal packing also features C-H?O inter-actions.

SUBMITTER: He G 

PROVIDER: S-EPMC3011640 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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2-Amino-pyridinium 1-phenyl-cyclo-propane-1-carboxyl-ate.

He Guangwen G   Aitipamula Srinivasulu S   Chow Pui Shan PS   Tan Reginald B H RB  

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12

In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (-), 2-amino-pyridine and 1-phenyl-cyclo-propane-1-carb-oxy-lic acid crystallize together, forming a 2-amino-pyridinium-carboxyl-ate supra-molecular heterosynthon involving two N-H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supra-molecular unit also sustained by N-H⋯O hydrogen bonding. A C-H⋯π inter-action between a pyridine C-H group and the centroid of the phenyl ring of the anion further stabilizes the four-component su  ...[more]

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