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Hydro-thermally synthesized ?-Ba(2)P(2)O(7).


ABSTRACT: Single crystals of ?-Ba(2)P(2)O(7), dibarium diphosphate, were obtained under hydro-thermal conditions. The structure belongs to the diphosphate A(2)P(2)O(7) series with A being an alkaline earth cation. ?-Ba(2)P(2)O(7) crystallizes isotypically with ?-Sr(2)P(2)O(7). All atomic sites have site symmetry m with the exception of two O atoms which reside on general positions. Both Ba(2+) cations are coordinated by nine terminal O atoms from eclipsed diphosphate P(2)O(7) anions to form a three-dimensional network throughout the structure.

SUBMITTER: Heyward C 

PROVIDER: S-EPMC3011656 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Hydro-thermally synthesized α-Ba(2)P(2)O(7).

Heyward Carla C   Mann Matthew M   Kolis Joseph J  

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12


Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained under hydro-thermal conditions. The structure belongs to the diphosphate A(2)P(2)O(7) series with A being an alkaline earth cation. α-Ba(2)P(2)O(7) crystallizes isotypically with α-Sr(2)P(2)O(7). All atomic sites have site symmetry m with the exception of two O atoms which reside on general positions. Both Ba(2+) cations are coordinated by nine terminal O atoms from eclipsed diphosphate P(2)O(7) anions to form a three-dimens  ...[more]

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