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(2SR,3SR)-Isopropyl 3-{[dimeth-yl(phenyl)-sil-yl]meth-yl}-2-hy-droxy-2-vinyl-pent-4-enoate.

ABSTRACT: The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si-C bond distances are in the range 1.858?(2)-1.880?(2)?Å and an intra-molecular O-H?O hydrogen bond helps to stabilize the mol-ecular conformation.

SUBMITTER: Nelson B

PROVIDER: S-EPMC3011670 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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(2SR,3SR)-Isopropyl 3-{[dimeth-yl(phenyl)-sil-yl]meth-yl}-2-hy-droxy-2-vinyl-pent-4-enoate.

Nelson Bjoern B Schürmann Markus M Preut Hans H Hiersemann Martin M

Acta crystallographica. Section E, Structure reports online 20101106 Pt 12

The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si-C bond distances are in the range 1.858 (2)-1.880 (2) Å and an intra-molecular O-H⋯O hydrogen bond helps to stabilize the mol-ecular conformation. ...[more]

PMID: 21589408

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