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2-(Methyl-sulfin-yl)benzamide.

ABSTRACT: In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl-sulfan-yl)benzamide using NaOCl with 2,2,6,6-tetra-methyl-piperidyl-1-oxy (TEMPO) as the catalyst, mol-ecules are linked via inter-molecular N-H?O(amide) hydrogen bonds, forming centrosymmetric amide-amide dimers which are extended into a two-dimensional lamellar framework parallel to (100) through amide-sulfinyl N-H?O hydrogen bonds. The benzene ring forms a dihedral angle of 25.6?(2)° with the amide group.

SUBMITTER: Yan Z

PROVIDER: S-EPMC3011674 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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2-(Methyl-sulfin-yl)benzamide.

Yan Zhou Z

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12

In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl-sulfan-yl)benzamide using NaOCl with 2,2,6,6-tetra-methyl-piperidyl-1-oxy (TEMPO) as the catalyst, mol-ecules are linked via inter-molecular N-H⋯O(amide) hydrogen bonds, forming centrosymmetric amide-amide dimers which are extended into a two-dimensional lamellar framework parallel to (100) through amide-sulfinyl N-H⋯O hydrogen bonds. The benzene ring forms a dihedral angle of 25.6 (2)° with the amide ...[more]

PMID: 21589589

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