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4,4'-Dibromo-7,7'-dimeth-oxy-1,1'-spiro-biindane.


ABSTRACT: In the title compound, C(19)H(18)Br(2)O(2), the dihedral angle between the two benzene rings of the spiro-biindane molecule is 70.44?(8)°. In the crystal, mol-ecules are inter-connected along the c axis by C-H?O hydrogen bonds and ?-? stacking [centroid-centroid distance = 3.893?(2)?Å] inter-actions, forming an infinite chain structure. The chains are further inter-connected through another set of C-H?O hydrogen bonds, forming layers approximately parallel to the bc plane.

SUBMITTER: Yao M 

PROVIDER: S-EPMC3011698 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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4,4'-Dibromo-7,7'-dimeth-oxy-1,1'-spiro-biindane.

Yao Min M   Ding Yanfeng Y   Wang Zi-Jia ZJ   Deng Yuheng Y  

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12


In the title compound, C(19)H(18)Br(2)O(2), the dihedral angle between the two benzene rings of the spiro-biindane molecule is 70.44 (8)°. In the crystal, mol-ecules are inter-connected along the c axis by C-H⋯O hydrogen bonds and π-π stacking [centroid-centroid distance = 3.893 (2) Å] inter-actions, forming an infinite chain structure. The chains are further inter-connected through another set of C-H⋯O hydrogen bonds, forming layers approximately parallel to the bc plane. ...[more]

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