Unknown

Dataset Information

0

Catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(1H-imidazol-1-yl)benzene].

ABSTRACT: In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis-(imidazol-1-yl)benzene ligands, generating a distorted tetra-hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the Zn(II) atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82?(13)°.

SUBMITTER: Nan Y 

PROVIDER: S-EPMC3011715 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[dichloridozinc(II)]-μ-1,4-bis-(1H-imidazol-1-yl)benzene].

Nan Yi Y   Yuan Ling L   Xu Cheng-Bi CB   Nan Shan-Ji SJ   Niu Yang Y  

Acta crystallographica. Section E, Structure reports online 20101106 Pt 12

In the title one-dimensional coordination polymer, [ZnCl(2)(C(12)H(10)N(4))](n), the Zn(II) atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis-(imidazol-1-yl)benzene ligands, generating a distorted tetra-hedral ZnCl(2)N(2) geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the Zn(II) atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and termin  ...[more]

Similar Datasets

Unknown catena-Poly[[[dichloridozinc(II)]-?-1,4-bis-(1H-benzimidazol-2-yl-?N)butane] 1,4-bis-(1H-benzimidazol-2-yl)butane solvate].
| S-EPMC2980004 | biostudies-literature
Unknown catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(3-pyridylmeth-yl)piperazine].
| S-EPMC2977589 | biostudies-literature
Unknown catena-Poly[[aqua-[1,4-bis-(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl-isophthalato].
| S-EPMC3200974 | biostudies-literature
Unknown catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(pyridin-2-ylmeth-oxy)benzene-?N:N'].
| S-EPMC3201249 | biostudies-literature
Unknown catena-Poly[[diformatocopper(II)]-?-1,4-bis-(imidazol-1-yl)benzene].
| S-EPMC3151804 | biostudies-other
Unknown catena-Poly[[[diaqua-diformatonickel(II)]-μ-1,4-bis-(1H-benzimidazol-1-yl)benzene] dihydrate].
| S-EPMC3274932 | biostudies-literature
Unknown catena-Poly[(dichloridozinc)-?-4,4'-bis-[(1H-imidazol-1-yl)meth-yl]biphenyl-?(2)N(3):N(3')].
| S-EPMC3344324 | biostudies-literature
Unknown catena-Poly[[[diaqua-manganese(II)]-bis-[μ-1,3-bis-(1H-imidazol-1-ylmeth-yl)benzene-κN:N]] dinitrate].
| S-EPMC3246916 | biostudies-literature
Unknown Poly[zinc(II)-[?-1,4-bis-(imidazol-1-yl-methyl)benzene]-?-4,4'-oxydibenzoato].
| S-EPMC2960729 | biostudies-literature
Unknown Poly[bis-[?-1,4-bis-(1H-imidazol-5-yl)benzene-?N:N]diformatomanganese(II)].
| S-EPMC3011459 | biostudies-other