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?-Decane-dioato-bis-[aqua-bis-(1,10-phenanthroline-?N,N')manganese(II)] dinitrate-sebacic acid-water (1/1/2).

ABSTRACT: In the title complex, [Mn(2)(C(10)H(16)O(4))(C(12)H(8)N(2))(4)(H(2)O)(2)](NO(3))(2)·C(10)H(18)O(4)·2H(2)O, the asymmetric unit contains one-half of the centrosymmetric dinuclear complex cation, one uncoordinated water molecule, one-half of a free sebaic acid (decanedioic acid) molecule that is also completed by inversion symmetry, and one disordered nitrate anion [occupancy ratio 0.454?(4):0.544?(6)]. The Mn(II) atoms are each octa-hedrally surrounded by four N atoms from two 1,10-phenanthroline (phen) ligands, one O atom from one carbonyl group of the bridging sebacate ligand and one O atom of a water mol-ecule. The crystal structure is stabilized by intermolecular O-H?O hydrogen bonds.

SUBMITTER: Feng YQ

PROVIDER: S-EPMC3050195 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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μ-Decane-dioato-bis-[aqua-bis-(1,10-phenanthroline-κN,N')manganese(II)] dinitrate-sebacic acid-water (1/1/2).

Feng Ye-Qiang YQ Long Jian J Li Juan J

Acta crystallographica. Section E, Structure reports online 20101215 Pt 1

In the title complex, [Mn(2)(C(10)H(16)O(4))(C(12)H(8)N(2))(4)(H(2)O)(2)](NO(3))(2)·C(10)H(18)O(4)·2H(2)O, the asymmetric unit contains one-half of the centrosymmetric dinuclear complex cation, one uncoordinated water molecule, one-half of a free sebaic acid (decanedioic acid) molecule that is also completed by inversion symmetry, and one disordered nitrate anion [occupancy ratio 0.454 (4):0.544 (6)]. The Mn(II) atoms are each octa-hedrally surrounded by four N atoms from two 1,10-phenanthroline ...[more]

PMID: 21522598

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