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Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-?C,S)bis-(triphenyl-phosphane-?P)molybdenum(II).

ABSTRACT: In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa-hedron. The phen-oxy-thio-carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by ?-? inter-molecular inter-actions and a supra-molecular aggregation is determined by inter-molecular C-H?O, C-H?Cl, C-H??(arene) hydrogen bonds and CO??(arene) inter-actions [O?centroid distances = 3.485?(4) and 3.722?(3)?Å].

SUBMITTER: Lee GH

PROVIDER: S-EPMC3050204 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-κC,S)bis-(triphenyl-phosphane-κP)molybdenum(II).

Lee Gene-Hsiang GH Wang Hsiao-Fen HF Yih Kuang-Hway KH Huang Shou-Ling SL

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa-hedron. The phen-oxy-thio-carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π-π inter-molecular inter-actions and a supra-molecular aggregation is determined by inter-molecular C-H⋯O, C-H⋯Cl, C-H⋯π(arene) hydrogen bonds and CO⋯π(arene) inter-actions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å]. ...[more]

PMID: 21522529

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