Unknown

Dataset Information

0

[(1,2,5,6-?)-Cyclo-octa-1,5-diene]bis-(4-methyl-phen-yl)platinum(II).

ABSTRACT: In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methyl-phenyl ligands and the mid-points of the two ?-coordinated double bonds of cyclo-octa-1,5-diene. The two methyl-phenyl groups have a cis relationship with a C-Pt-C bond angle of 88.54?(18)° and a dihedral angle between the mean planes of the benzene rings of 83.87?(1)°. Each complex mol-ecule links to four symmetry-related ones through inter-molecular C-H?? inter-actions, forming a layer almost parallel to the bc plane.

SUBMITTER: Wang ZW 

PROVIDER: S-EPMC3050351 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

[(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(4-methyl-phen-yl)platinum(II).

Wang Zhi-Wei ZW   Liu Ran R   Liu Hong-Yu HY   Wan Chong-Qing CQ  

Acta crystallographica. Section E, Structure reports online 20101204 Pt 1

In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methyl-phenyl ligands and the mid-points of the two π-coordinated double bonds of cyclo-octa-1,5-diene. The two methyl-phenyl groups have a cis relationship with a C-Pt-C bond angle of 88.54 (18)° and a dihedral angle between the mean planes of the benzene rings of 83.87 (1)°. Each complex mol-ecule links to four symmetry-related ones through inter-molecula  ...[more]

Similar Datasets

Unknown Bromido[(1,2,5,6-?)-cyclo-octa-1,5-diene]methyl-platinum(II).
| S-EPMC2980049 | biostudies-literature
Unknown Chloridocyclo-hexyl[(1,2,5,6-η)-cyclo-octa-1,5-diene]platinum(II).
| S-EPMC2971967 | biostudies-literature
Unknown [(1,2,5,6-?)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate.
| S-EPMC3238752 | biostudies-literature
Unknown Crystal structure of chlorido-bis-[(1,2,5,6-?)-cyclo-octa-1,5-diene]iridium(I).
| S-EPMC5290581 | biostudies-literature
Unknown Bis[1,2-bis-(dimethyl-phosphino)ethane-?P,P']rhodium(I) dichlorido[(1,2,5,6-?)-1,5-cyclo-octa-diene]rhodium(I).
| S-EPMC2959718 | biostudies-literature
Unknown Crystal structures of (?4-cyclo-octa-1,5-diene)bis(1,3-di-methyl-imidazol-2-yl-idene)iridium(I) iodide and (?4-cyclo-octa-1,5-diene)bis-(1,3-di-ethyl-imidazol-2-yl-idene)iridium(I) iodide.
| S-EPMC7199247 | biostudies-literature
Unknown [(1,2,5,6-?)-1,5-Cyclo-octa-diene](1-isopropyl-3-methyl-imidazolin-2-yl-idene)(triphenyl-phosphine)iridium(I) tetra-fluorido-borate dichloro-methane solvate.
| S-EPMC3008037 | biostudies-literature
Unknown Dichlorido(?-cyclo-octa-1,5-diene)bis-(triphenyl-phosphine)osmium(II).
| S-EPMC2970349 | biostudies-literature
Unknown Bis(acrylonitrile-?N)dichlorido(?-cyclo-octa-1,5-diene)ruthenium(II).
| S-EPMC3201466 | biostudies-literature
Unknown (18-Crown-6)potassium [(1,2,5,6-?)-cyclo-octa-1,5-diene][(1,2,3,4-?)-naph-tha-lene]-ferrate(-I).
| S-EPMC3470125 | biostudies-literature