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Tris(methylammonium thiocyanurate) monohydrate.

ABSTRACT: In the title compound, 3[(CH(3))(3)HN(+)]·3C(3)H(2)N(3)S(3) (-)·H(2)O, two independent trithio-cyanurate anions construct a planar hydrogen-bonded ribbon with two N-H?S hydrogen bonds linking each pair of adjacent anions in the chain. The third independent anion and the water mol-ecule form a chain by way of N-H?S and O-H?S contacts, which propagates parallel to the ribbon. The chains and ribbons are cross-linked by O-H?S hydrogen bonds, generating sheets. The three independent trimethyl-ammonium cations are contained between the sheets by way of various N-H?S and N-H?N contacts.

SUBMITTER: Hou Y

PROVIDER: S-EPMC3050359 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Tris(methylammonium thiocyanurate) monohydrate.

Hou Yimin Y Yang Yunxia Y

Acta crystallographica. Section E, Structure reports online 20101208 Pt 1

In the title compound, 3[(CH(3))(3)HN(+)]·3C(3)H(2)N(3)S(3) (-)·H(2)O, two independent trithio-cyanurate anions construct a planar hydrogen-bonded ribbon with two N-H⋯S hydrogen bonds linking each pair of adjacent anions in the chain. The third independent anion and the water mol-ecule form a chain by way of N-H⋯S and O-H⋯S contacts, which propagates parallel to the ribbon. The chains and ribbons are cross-linked by O-H⋯S hydrogen bonds, generating sheets. The three independent trimethyl-ammoniu ...[more]

PMID: 21522753

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