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Bis{2-[3-(dimethyl-amino)-propyl-imino-meth-yl]-6-meth-oxy-phenolato}-?N,N',O;?N,O-zinc(II) dihydrate.

ABSTRACT: In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter-molecular O-H?O and O-H?N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H?O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].

SUBMITTER: Lin H

PROVIDER: S-EPMC3050366 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Bis{2-[3-(dimethyl-amino)-propyl-imino-meth-yl]-6-meth-oxy-phenolato}-κN,N',O;κN,O-zinc(II) dihydrate.

Lin Hong H Wang Xiao-Juan XJ

Acta crystallographica. Section E, Structure reports online 20101218 Pt 1

In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize th ...[more]

PMID: 21522605

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