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Acridine-benzene-1,3,5-tricarb-oxy-lic acid (3/1).

ABSTRACT: In the title adduct, 3C(13)H(9)N·C(9)H(6)O(6) or (acr)(3)(btc), associ-ations of one btc and three acr molecules linked by O-H?N hydrogen bonds occur. C-H?O interactions also occur, resulting in a cyclic hydrogen-bonded synthon R(2) (1)(6). The acr mol-ecules and the btc mol-ecules also form slipped or offset ?-? stacking inter-actions [centroid-centroid distances of 3.5212?(17)?Å for btc rings and 3.703?(2) and 3.731?(2)?Å for acr rings]. Together these inter-actions lead to a three-dimensional network.

SUBMITTER: Aghabozorg H

PROVIDER: S-EPMC3050414 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Acridine-benzene-1,3,5-tricarb-oxy-lic acid (3/1).

Aghabozorg Hossein H Goodarzi Saba S Mirzaei Masoud M Notash Behrouz B

Acta crystallographica. Section E, Structure reports online 20101215 Pt 1

In the title adduct, 3C(13)H(9)N·C(9)H(6)O(6) or (acr)(3)(btc), associ-ations of one btc and three acr molecules linked by O-H⋯N hydrogen bonds occur. C-H⋯O interactions also occur, resulting in a cyclic hydrogen-bonded synthon R(2) (1)(6). The acr mol-ecules and the btc mol-ecules also form slipped or offset π-π stacking inter-actions [centroid-centroid distances of 3.5212 (17) Å for btc rings and 3.703 (2) and 3.731 (2) Å for acr rings]. Together these inter-actions lead to a three-dimensional ...[more]

PMID: 21522637

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