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Trisilver(I) citrate.

ABSTRACT: Trisilver(I) citrate, 3Ag(+)·C(6)H(5)O(7) (3-), was obtained by evaporation of a saturated aqueous solution of the raw material that had been obtained from sodium dihydrogen citrate and silver nitrate. It features one formula unit in the asymmetric unit. There is an intra-molecular O-H?O hydrogen bond between the OH group and one of the terminal carboxyl-ate groups. Different citrate groups are linked via the three Ag(+) ions, yielding a three-dimensional network with rather irregular [AgO(4)] polyhedra.

SUBMITTER: Fischer A

PROVIDER: S-EPMC3051445 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Trisilver(I) citrate.

Fischer Andreas A

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

Trisilver(I) citrate, 3Ag(+)·C(6)H(5)O(7) (3-), was obtained by evaporation of a saturated aqueous solution of the raw material that had been obtained from sodium dihydrogen citrate and silver nitrate. It features one formula unit in the asymmetric unit. There is an intra-molecular O-H⋯O hydrogen bond between the OH group and one of the terminal carboxyl-ate groups. Different citrate groups are linked via the three Ag(+) ions, yielding a three-dimensional network with rather irregular [AgO(4)] p ...[more]

PMID: 21522908

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