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4-Bromo-2-{[(pyridin-3-ylmeth-yl)imino]-meth-yl}phenol.

ABSTRACT: The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra-molecular O-H?N hydrogen bonding between the hy-droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7?(1)°. In the crystal, the mol-ecules are stacked in columns along the c axis and several inter-molecular ?-? inter-actions are present between the six-membered rings, with a shortest centroid-centroid distance of 3.707?(2)?Å.

SUBMITTER: Ha K 

PROVIDER: S-EPMC3051591 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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4-Bromo-2-{[(pyridin-3-ylmeth-yl)imino]-meth-yl}phenol.

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra-molecular O-H⋯N hydrogen bonding between the hy-droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the mol-ecules are stacked in columns along the c axis and several inter-molecular π-π inter-actions are present between the six-membered rings, with a shortest centroid-centroid distance of 3.707 (2) Å. ...[more]

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