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Di-tert-Butyl 2,2'-[2,2'-methyl-enebis(naphthalene-2,1-diyldi-oxy)]diacetate.

ABSTRACT: In the title compound, C(33)H(36)O(6), two naphthalene ring systems are connected through a methyl-ene linkage [C-C-C = 114.9?(2)°]; the ring systems are aligned at an angle of 76.5?(1)°. Of the two -O-CH(2)-C(=O)-C(CH(3))(3) substituents, one adopts an extended conformation whereas the other is U-shaped. In the crystal, mol-ecules are linked via weak C-H?O hydrogen bonding, forming supra-molecular chains running along the c axis.

SUBMITTER: Ali Q

PROVIDER: S-EPMC3051626 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Di-tert-Butyl 2,2'-[2,2'-methyl-enebis(naphthalene-2,1-diyldi-oxy)]diacetate.

Ali Qamar Q Anis Itrat I Raza Shah M M Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

In the title compound, C(33)H(36)O(6), two naphthalene ring systems are connected through a methyl-ene linkage [C-C-C = 114.9 (2)°]; the ring systems are aligned at an angle of 76.5 (1)°. Of the two -O-CH(2)-C(=O)-C(CH(3))(3) substituents, one adopts an extended conformation whereas the other is U-shaped. In the crystal, mol-ecules are linked via weak C-H⋯O hydrogen bonding, forming supra-molecular chains running along the c axis. ...[more]

PMID: 21523181

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