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1'-Methyl-3'-(4-methyl-benzo-yl)-4'-[5-(2-thien-yl)-2-thien-yl]spiro-[acenaphthyl-ene-1,2'-pyrrolidin]-2(1H)-one.

ABSTRACT: In the title compound, C(32)H(25)NO(2)S(2), the mean plane through the five-membered pyrrolidine ring, which exhibits an envelope conformation, makes dihedral angles of 82.3?(1) and 83.9?(9)° with the benzene ring and the acenaphthyl-ene ring system, respectively. The dihedral angle between the thiophene rings is 19.0(3)°. The crystal structure shows C-H?? and ?-? inter-actions [centroid-centroid distance = 3.869?(2)?Å].

SUBMITTER: Thenmozhi S

PROVIDER: S-EPMC3051628 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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1'-Methyl-3'-(4-methyl-benzo-yl)-4'-[5-(2-thien-yl)-2-thien-yl]spiro-[acenaphthyl-ene-1,2'-pyrrolidin]-2(1H)-one.

Thenmozhi S S Govindan E E Gavaskar D D Raghunathan R R Subbiahpandi A A

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

In the title compound, C(32)H(25)NO(2)S(2), the mean plane through the five-membered pyrrolidine ring, which exhibits an envelope conformation, makes dihedral angles of 82.3 (1) and 83.9 (9)° with the benzene ring and the acenaphthyl-ene ring system, respectively. The dihedral angle between the thiophene rings is 19.0(3)°. The crystal structure shows C-H⋯π and π-π inter-actions [centroid-centroid distance = 3.869 (2) Å]. ...[more]

PMID: 21522959

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