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Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}manganese(II).

ABSTRACT: The asymmetric unit of the title compound, [MnCl(2)(C(11)H(17)N(3))], contains two crystallographically independent mol-ecules with slightly different geometries. In each mol-ecule, the Mn(II) ion is five coordinated by the N,N',N''-tridentate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. In the crystal, C-H?Cl hydrogen bonds link adjacent mol-ecules into a three-dimensional network.

SUBMITTER: Ikmal Hisham NA

PROVIDER: S-EPMC3051723 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}manganese(II).

Ikmal Hisham Nurul Azimah NA Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

The asymmetric unit of the title compound, [MnCl(2)(C(11)H(17)N(3))], contains two crystallographically independent mol-ecules with slightly different geometries. In each mol-ecule, the Mn(II) ion is five coordinated by the N,N',N''-tridentate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. In the crystal, C-H⋯Cl hydrogen bonds link adjacent mol-ecules into a three-dimensional network. ...[more]

PMID: 21522887

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