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Bis(acetato-?O,O')bis-[4-(dimethyl-amino)-pyridine-?N]copper(II).

ABSTRACT: In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl-amino)-pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate anions, which are asymmetrically bonded in the equatorial plane. The complex and the crystal packing of the complex are stabilized by intra- and inter-molecular C-H?O hydrogen bonds, giving R(4) (2)(10) rings and generating a layer-like structure.

SUBMITTER: Benslimane M

PROVIDER: S-EPMC3051772 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Bis(acetato-κO,O')bis-[4-(dimethyl-amino)-pyridine-κN]copper(II).

Benslimane Meriem M Merazig Hocine H Daran Jean-Claude JC

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl-amino)-pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate anions, which are asymmetrically bonded in the equatorial plane. The complex and the crystal packing of the complex are stabilized by intra- and inter-molecular C-H⋯O hydrogen bonds, giving R(4) (2)(10 ...[more]

PMID: 21522891

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