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4-tert-Butyl-pyridinium triiodide-4-tert-butyl-pyridine (1/1).

ABSTRACT: The title compound, C(9)H(14)N(+)·I(3) (-)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl-pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105?(4)?Å (I-I) and a bond angle of 177.55?(3)° (I-I-I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotator, modeled in three separate positions with 1/3, 1/3, 1/3 occupancies. The cations assemble into dimeric forms by way of N-H?N hydrogen bonds.

SUBMITTER: He H

PROVIDER: S-EPMC3051785 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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4-tert-Butyl-pyridinium triiodide-4-tert-butyl-pyridine (1/1).

He Hongshan H Sykes Andrew G AG

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

The title compound, C(9)H(14)N(+)·I(3) (-)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl-pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I-I) and a bond angle of 177.55 (3)° (I-I-I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotator, modeled in three separate positions with 1/3, 1/3, 1/3 occupancies. The cations assemble into dimeri ...[more]

PMID: 21523100

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