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Redetermination of AgPO(3).


ABSTRACT: Single crystals of silver(I) polyphosphate(V), AgPO(3), were prepared via a phospho-ric acid melt method using a solution of Ag(3)PO(4) in H(3)PO(4). In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ?). Acta Cryst. 14, 779-784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO(5)] polyhedra, giving rise to multidirectional ribbons, and from two types of PO(4) tetra-hedra linked into meandering chains (PO(3))(n) spreading parallel to the b axis with a repeat unit of four tetra-hedra. The calculated bond-valence sum value of one of the two Ag(I) ions indicates a significant strain of the structure.

SUBMITTER: Terebilenko KV 

PROVIDER: S-EPMC3052054 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Redetermination of AgPO(3).

Terebilenko Katherina V KV   Zatovsky Igor V IV   Ogorodnyk Ivan V IV   Baumer Vyacheslav N VN   Slobodyanik Nikolay S NS  

Acta crystallographica. Section E, Structure reports online 20110209 Pt 3


Single crystals of silver(I) polyphosphate(V), AgPO(3), were prepared via a phospho-ric acid melt method using a solution of Ag(3)PO(4) in H(3)PO(4). In comparison with the previous study based on single-crystal Weissenberg photographs [Jost (1961 ▶). Acta Cryst. 14, 779-784], the results were mainly confirmed, but with much higher precision and with all displacement parameters refined anisotropically. The structure is built up from two types of distorted edge- and corner-sharing [AgO(5)] polyhe  ...[more]

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