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(2,2'-Bipyridyl-?N,N')bis-(N-butyl-N-methyl-dithio-carbamato-?S,S')cadmium(II).

ABSTRACT: The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa-coordinated by two dithio-carbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl mol-ecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N(2)S(4) donor set. Supra-molecular chains, aligned along the a-axis direction, are mediated by C-H?S inter-actions and these are connected into layers that stack along the c axis via ?-? inter-actions [Cg(pyrid-yl)?Cg(pyrid-yl) = 3.6587?(13)?Å].

SUBMITTER: Jamaluddin NA

PROVIDER: S-EPMC3052129 | biostudies-literature | 2011

REPOSITORIES: biostudies-literature

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(2,2'-Bipyridyl-κN,N')bis-(N-butyl-N-methyl-dithio-carbamato-κS,S')cadmium(II).

Jamaluddin Nur Amirah NA Baba Ibrahim I Mohamed Tahir Mohamed Ibrahim MI Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110226 Pt 3

The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa-coordinated by two dithio-carbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl mol-ecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N(2)S(4) donor set. Supra-molecular chains, aligned along the a-axis direction, are mediated by C-H⋯S inter-actions and these are connected into layers that stack along the c axis via π-π inter-actions [Cg(pyrid-yl)⋯Cg(pyr ...[more]

PMID: 21522303

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