Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-Bromo-2-[(E)-(4-fluoro-phen-yl)imino-meth-yl]phenol.

ABSTRACT: In the title compound, C(13)H(9)BrFNO, the dihedral angle between the substituted benzene rings is 9.00?(11)°. Strong intra-molecular O-H?N hydrogen bonds generate S(6) ring motifs.

SUBMITTER: Ardakani AA

PROVIDER: S-EPMC3052130 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

4-Bromo-2-[(E)-(4-fluoro-phen-yl)imino-meth-yl]phenol.

Ardakani Amir Adabi AA Kia Reza R Kargar Hadi H Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20110212 Pt 3

In the title compound, C(13)H(9)BrFNO, the dihedral angle between the substituted benzene rings is 9.00 (11)°. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. ...[more]

PMID: 21522357

Similar Datasets

2-[(3-Bromo-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(13)H(10)BrNO, was prepared by reaction of 3-bromo-aniline with 2-hydroxy-benzaldehyde at 377?K. The mol-ecular structure and packing are stabilized by an intra-molecular O-H?N hydrogen-bond inter-action.

| S-EPMC2960578 | biostudies-literature

4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.

Project description:In the title compound, C(14)H(11)BrN(2)O(2), the mean planes of the two benzene rings are almost parallel to each other, making a dihedral angle of 4.09?(1)°. An intra-molecular O-H?N hydrogen bond occurs. In the crystal, inter-molecular O-H?N and C-H?O hydrogen bonds link the mol-ecules into a chain-like supra-molecular structure.

| S-EPMC3007216 | biostudies-literature

2-[(2-Bromo-phen-yl)imino-meth-yl]-6-methyl-phenol.

Project description:In the title compound, C(14)H(12)BrNO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the two aromatic rings is 34.26?(9)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring.

| S-EPMC3009115 | biostudies-literature

4-Fluoro-2-[(3-methyl-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(14)H(12)FNO, crystallizes as the trans phenol-imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28?(7)°. This is at least in part due to the intra-molecular O-H?N hydrogen bond between the hy-droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C-H?O and C-H?F inter-actions, which link the mol-ecules into a stable three-dimensional network.

| S-EPMC3344028 | biostudies-literature

(E)-4-[(4-Bromo-phen-yl)imino-meth-yl]-2-meth-oxy-phenol.

Project description:In the crystal structure of the title compound, C(14)H(12)BrNO(2), the dihedral angle between the rings is 37.87 (10)° and the mol-ecule has an E conformation about the central C=N bond. In the crystal, mol-ecules are connected by inter-molecular O-H⋯N hydrogen bonds into zigzag chains running parallel to the b axis. The packing also features C-H⋯O inter-actions.

| S-EPMC3414922 | biostudies-literature

(E)-4-Bromo-2-[(2,6-diisopropyl-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(19)H(22)BrNO, the dihedral angle between the benzene rings is 76.17?(14)° and an intra-molecular O-H?N hydrogen bond with an S(6) graph-set motif is present. One methyl group is disordered over two sets of sites with site occupancies of 0.66?(3) and 0.34?(3). A weak inter-molecular C-H?? inter-action is observed in the crystal structure.

| S-EPMC3379361 | biostudies-literature

(E)-4-Bromo-2-[(4-ethyl-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(15)H(14)BrNO, the dihedral angle between the two benzene rings is 43.99?(2)°. The mol-ecular conformation is influenced by an intra-molecular O-H?N hydrogen bond.

| S-EPMC2915047 | biostudies-literature

4-Bromo-2-{(E)-[(3,4-dimethyl-phen-yl)imino]-meth-yl}phenol.

Project description:In the title compound, C(15)H(14)BrNO, the dihedral angle between the aromatic rings is 4.10?(11)° and the mol-ecule is close to planar (r.m.s. deviation for the non-H atoms = 0.053?Å). An intra-molecular O-H?N hydrogen bond closes an S(6) ring. In the crystal, very weak C-H?? inter-actions are observed.

| S-EPMC3435742 | biostudies-literature

4-Bromo-2-[(E)-(4-chloro-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(13)H(9)BrClNO, the dihedral angle between the substituted benzene rings is 43.90?(11)°. Strong intra-molecular O-H?N hydrogen bonds generate S(6) ring motifs. The crystal structure features short intemolecular Br?Br [3.554?(2)?Å] and Cl?Cl [3.412?(2)?Å] contacts. The crystal packing is further stabilized by inter-molecular C-H?O and C-H?? inter-actions.

| S-EPMC3052075 | biostudies-literature

(E)-2-[(3-Fluoro-phen-yl)imino-meth-yl]-4-(trifluoro-meth-oxy)phenol.

Project description:The title compound, C(14)H(9)F(4)NO(2), is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The H atom is located on the hydr-oxy O atom rather than on the N atom. This H atom is involved in a strong intra-molecular O-H?N hydrogen bond. The mol-ecule is almost planar, the angle between the benzene rings being 2.14?(13)°.

| S-EPMC2983675 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data