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Bis[N-(2-hy-droxy-eth-yl)-N-propyl-dithio-carbamato-?S,S']bis-(4-{[(pyridin-4-yl-methyl-idene)hydrazinyl-idene]meth-yl}pyridine-?N)cadmium.

ABSTRACT: The complete mol-ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa-hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S'-chelating dithio-carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine-aldazine (or 4-{[(pyridin-4-yl-methyl-idene)hydrazinyl-idene}meth-yl]pyridine) mol-ecules [dihedral angle between the aromatic rings = 17.33?(8)°]. In the crystal, mol-ecules are connected into a supra-molecular chain via O-H?N hydrogen bonds involving the 4-pyridine-aldazine N atoms not involved in coordination to cadmium. Weak C-H?O and C-H?N links consolidate the packing.

SUBMITTER: Broker GA

PROVIDER: S-EPMC3052135 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Bis[N-(2-hy-droxy-eth-yl)-N-propyl-dithio-carbamato-κS,S']bis-(4-{[(pyridin-4-yl-methyl-idene)hydrazinyl-idene]meth-yl}pyridine-κN)cadmium.

Broker Grant A GA Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110212 Pt 3

The complete mol-ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa-hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S'-chelating dithio-carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine-aldazine (or 4-{[(pyridin-4-yl-methyl-idene)hydrazinyl-idene}meth-yl]pyridine) mol-ecules [dihedral angle between the aromatic rings = 17.33 (8)°]. In ...[more]

PMID: 21522253

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