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Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl-idene]ethanamine-?N,N',N''}copper(II) monohydrate.

ABSTRACT: In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H?Cl hydrogen bonds link the complex mol-ecules and the uncoordinated water mol-ecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H?O and C-H?Cl inter-actions.

SUBMITTER: Suleiman Gwaram N

PROVIDER: S-EPMC3052153 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl-idene]ethanamine-κN,N',N''}copper(II) monohydrate.

Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20110212 Pt 3

In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H⋯Cl hydrogen bonds link the complex mol-ecules and the uncoordinated water mol-ecules into infinite chains along the a axis. The chains are further connected into a ...[more]

PMID: 21522265

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