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Toward the total synthesis of maoecrystal V: an intramolecular Diels-Alder route to the maoecrystal V pentacyclic core with the appropriate relative stereochemistry.

ABSTRACT: A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels-Alder cyclization and an exo-glycal epoxide rearrangement sequence.

SUBMITTER: Peng F

PROVIDER: S-EPMC3079889 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Toward the total synthesis of maoecrystal V: an intramolecular Diels-Alder route to the maoecrystal V pentacyclic core with the appropriate relative stereochemistry.

Peng Feng F Danishefsky Samuel J SJ

Tetrahedron letters 20110401 17

A diastereoselective route to the maoecrystal V core compound (6) has been achieved. Key transformations include an intramolecular Diels-Alder cyclization and an exo-glycal epoxide rearrangement sequence. ...[more]

PMID: 21516211

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