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Self-Assembly of Coordinative Supramolecular Polygons with Open Binding Sites.

ABSTRACT: The design and synthesis of coordinative supramolecular polygons with open binding sites is described. Coordination-driven self-assembly of 2,6-bis(pyridin-4-ylethynyl)pyridine with 60° and 120° organoplatinum acceptors results in quantitative formation of a supramolecular rhomboid and hexagon, respectively, both bearing open pyridyl binding sites. The structures were determined by multinuclear ((31)P and (1)H) NMR spectroscopy and electrospray ionization (ESI) mass spectrometry, along with a computational study.

SUBMITTER: Zheng YR

PROVIDER: S-EPMC3079920 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Self-Assembly of Coordinative Supramolecular Polygons with Open Binding Sites.

Zheng Yao-Rong YR Wang Ming M Kobayashi Shiho S Stang Peter J PJ

Tetrahedron letters 20110401 17

The design and synthesis of coordinative supramolecular polygons with open binding sites is described. Coordination-driven self-assembly of 2,6-bis(pyridin-4-ylethynyl)pyridine with 60° and 120° organoplatinum acceptors results in quantitative formation of a supramolecular rhomboid and hexagon, respectively, both bearing open pyridyl binding sites. The structures were determined by multinuclear ((31)P and (1)H) NMR spectroscopy and electrospray ionization (ESI) mass spectrometry, along with a co ...[more]

PMID: 21516167

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