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Suzuki-Miyaura cross-coupling of 3-pyridyl triflates with 1-alkenyl-2-pinacol boronates.

ABSTRACT: Palladium-catalyzed Suzuki-type couplings of 3-pyridyl triflates with alkenyl pinacol boronates proceed in good to excellent yield. Optimized conditions use Pd(PPh(3))(4) (10 mol %) as catalyst with K(3)PO(4) (3 equiv) as base in dioxane.

SUBMITTER: Vyvyan JR 

PROVIDER: S-EPMC3080250 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Suzuki-Miyaura cross-coupling of 3-pyridyl triflates with 1-alkenyl-2-pinacol boronates.

Vyvyan James R JR   Dell Née Meyer Jennifer A JA   Ligon Toby J TJ   Motanic Kelsey K KK   Wall Hayley S HS  

Synthesis 20101101 21

Palladium-catalyzed Suzuki-type couplings of 3-pyridyl triflates with alkenyl pinacol boronates proceed in good to excellent yield. Optimized conditions use Pd(PPh(3))(4) (10 mol %) as catalyst with K(3)PO(4) (3 equiv) as base in dioxane. ...[more]

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