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(2E)-2-[2-(Cyclo-hexyl-carbamothio-yl)hydrazinylidene]-propanoic acid.

ABSTRACT: In the title thio-urea derivative, C(10)H(17)N(3)O(2)S, the carboxyl group and the least-squares plane through the cyclo-hexyl ring are twisted out of the plane through the central CN(3)S residue; the respective dihedral angles are 7.18?(8) and 62.29?(4)°. The conformation about the azomethine bond [1.275?(2)?Å] is E. The NH groups are anti, with one forming an intra-molecular N-H?N hydrogen bond. The main feature of the crystal structure is the formation of linear supra-molecular chains along [110] mediated by alternating pairs of O-H?O and pairs of N-H?S hydrogen bonds.

SUBMITTER: Affan MA

PROVIDER: S-EPMC3089072 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(2E)-2-[2-(Cyclo-hexyl-carbamothio-yl)hydrazinylidene]-propanoic acid.

Affan Md Abu MA Salam Md Abdus MA Ahmad Fasihuddin B FB Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110422 Pt 5

In the title thio-urea derivative, C(10)H(17)N(3)O(2)S, the carboxyl group and the least-squares plane through the cyclo-hexyl ring are twisted out of the plane through the central CN(3)S residue; the respective dihedral angles are 7.18 (8) and 62.29 (4)°. The conformation about the azomethine bond [1.275 (2) Å] is E. The NH groups are anti, with one forming an intra-molecular N-H⋯N hydrogen bond. The main feature of the crystal structure is the formation of linear supra-molecular chains along [ ...[more]

PMID: 21754495

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