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(5,5'-Dimethyl-2,2'-bipyridine)-iodido-trimethyl-platinum(IV).

ABSTRACT: In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa-hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand.

SUBMITTER: Lundvall F

PROVIDER: S-EPMC3089208 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(5,5'-Dimethyl-2,2'-bipyridine)-iodido-trimethyl-platinum(IV).

Lundvall Fredrik F Wragg David Stephen DS Tilset Mats M

Acta crystallographica. Section E, Structure reports online 20110422 Pt 5

In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa-hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand. ...[more]

PMID: 21754331

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