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Dichlorido[bis-(2-ethyl-5-methyl-1H-imidazol-4-yl-?N)methane]-cobalt(II) monohydrate.

ABSTRACT: In the title compound, [CoCl(2)(C(13)H(20)N(4))]·H(2)O, the Co(II) atom lies on a mirror plane and is four-coordinated by two N atoms of the imidazole ligand and two Cl atoms in a distorted tetra-hedral arrangement. The water mol-ecule participates in the formation of hydrogen bonds, resulting in a three dimensional network involving the Cl atoms and the NH groups. The terminal C atom of the ethyl group is disordered over two sites of equal occupancy.

SUBMITTER: Qian XM 

PROVIDER: S-EPMC3089236 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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Dichlorido[bis-(2-ethyl-5-methyl-1H-imidazol-4-yl-κN)methane]-cobalt(II) monohydrate.

Qian Xiao-Min XM   Luo Yang-Hui YH   Li Jin-Feng JF   Mao Shu-Lin SL   Gao Ge G  

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

In the title compound, [CoCl(2)(C(13)H(20)N(4))]·H(2)O, the Co(II) atom lies on a mirror plane and is four-coordinated by two N atoms of the imidazole ligand and two Cl atoms in a distorted tetra-hedral arrangement. The water mol-ecule participates in the formation of hydrogen bonds, resulting in a three dimensional network involving the Cl atoms and the NH groups. The terminal C atom of the ethyl group is disordered over two sites of equal occupancy. ...[more]

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