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(Benzyl phenyl sulfoxide-?O)dichloridodiphenyl-tin(IV).

ABSTRACT: The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal-bipyramidal coordination environment, with a mean Sn-C distance of 2.121?(9)?Å and with Sn-O = 2.331?(2)?Å. The Sn(IV) atom is displaced by 0.169?(2)?Å from the equatorial C(2)Cl plane towards the direction of the second axially bonded Cl atom.

SUBMITTER: Tan GX

PROVIDER: S-EPMC3089264 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(Benzyl phenyl sulfoxide-κO)dichloridodiphenyl-tin(IV).

Tan Guo-Xia GX Zhang Chang-Fa CF Liu Xi-Cheng XC

Acta crystallographica. Section E, Structure reports online 20110429 Pt 5

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal-bipyramidal coordination environment, with a mean Sn-C distance of 2.121 (9) Å and with Sn-O = 2.331 (2) Å. The Sn(IV) atom is displaced by 0.169 (2) Å from the equatorial C(2)Cl plane towards the direction of the second axially bonded Cl atom. ...[more]

PMID: 21754340

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