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4-({[(E)-Pyridin-3-yl-methyl-idene]amino}-meth-yl)cyclo-hexa-necarb-oxy-lic acid.

ABSTRACT: The title compound, C(14)H(18)N(2)O(2), contains two geometrically different mol-ecules in the asymmetric unit: the basal plane of the cyclo-hexane chair and the N-[pyridin-3-yl-methyl-idene]methanamine moiety are oriented at dihedral angles of 71.77?(7)° and 83.42?(8)°. In the crystal, the mol-ecules are linked by O-H?N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R(2) (2)(26) ring motifs are formed due to the C-H?·O inter-actions that link neighbouring chains. There also exist ?-? inter-actions [centroid-centroid separation = 3.6925?(12)?Å] between the symmetry-related pyridine rings of one of the independent mol-ecules.

SUBMITTER: Nisar M

PROVIDER: S-EPMC3089300 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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4-({[(E)-Pyridin-3-yl-methyl-idene]amino}-meth-yl)cyclo-hexa-necarb-oxy-lic acid.

Nisar Muhammad M Ali Ihsan I Tahir M Nawaz MN Qayum Mughal M Marwat Inamullah Khan IK

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

The title compound, C(14)H(18)N(2)O(2), contains two geometrically different mol-ecules in the asymmetric unit: the basal plane of the cyclo-hexane chair and the N-[pyridin-3-yl-methyl-idene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the mol-ecules are linked by O-H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R(2) (2)(26) ring motifs are formed due to the C-H⋯·O inter-actions that link neighbo ...[more]

PMID: 21754384

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