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N-Methyl-4-(4-pivalamido-phenyl-sulfan-yl)picolinamide hemihydrate.

ABSTRACT: In the title compound, C(18)H(21)N(3)O(2)S·0.5H(2)O, the benzene ring makes dihedral angles of 88.59?(6) and 40.74?(8)° with the pyridine ring and the amide group, respectively. The water O atom lies on a twofold axis. In the crystal, the organic mol-ecules and the water mol-ecules are linked via O-H?O hydrogen bonds, while the organic mol-ecules are connected to each other via N-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Ye TH

PROVIDER: S-EPMC3089303 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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N-Methyl-4-(4-pivalamido-phenyl-sulfan-yl)picolinamide hemihydrate.

Ye Ting-Hong TH Huang Ting-Ting TT Shi Yao-Jie YJ Xiong Ying Y Yu Luo-Ting LT

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

In the title compound, C(18)H(21)N(3)O(2)S·0.5H(2)O, the benzene ring makes dihedral angles of 88.59 (6) and 40.74 (8)° with the pyridine ring and the amide group, respectively. The water O atom lies on a twofold axis. In the crystal, the organic mol-ecules and the water mol-ecules are linked via O-H⋯O hydrogen bonds, while the organic mol-ecules are connected to each other via N-H⋯O hydrogen bonds, forming a three-dimensional network. ...[more]

PMID: 21754418

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