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Cyclo-Tetrakis(?(2)-3-sulfidopropyl-?C,S:S)tetrakis[chloridocobalt(III)].

ABSTRACT: In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra-hedral geometry by one C, one Cl and two S atoms. The mol-ecules are stabilized by C-H?Cl hydrogen bonds. In the crystal, inter-molecular C-H?Cl and C-H?S hydrogen bonds with R(2) (2)(8), R(4) (2)(8) and R(2) (2)(6) ring motifs generate a polymeric network.

SUBMITTER: Awan SA

PROVIDER: S-EPMC3089308 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κC,S:S)tetrakis[chloridocobalt(III)].

Awan Shafique Ahmad SA Tahir M Nawaz MN Muhammad Iram Khushi IK Ahmad Saeed S Tariq Muhammad Ilyas MI

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra-hedral geometry by one C, one Cl and two S atoms. The mol-ecules are stabilized by C-H⋯Cl hydrogen bonds. In the crystal, inter-molecular C-H⋯Cl and C-H⋯S hydrogen bonds with R(2) (2)(8), R(4) (2)(8) and R(2) (2)(6) ring motifs generate a polymeric network. ...[more]

PMID: 21754303

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