Browse
Submit Data
Databases
API
Help

Dataset Information

15 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Cyclo-Tetrakis(?(2)-3-sulfidopropyl-?C,S:S)tetrakis[chloridocobalt(III)].

ABSTRACT: In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra-hedral geometry by one C, one Cl and two S atoms. The mol-ecules are stabilized by C-H?Cl hydrogen bonds. In the crystal, inter-molecular C-H?Cl and C-H?S hydrogen bonds with R(2) (2)(8), R(4) (2)(8) and R(2) (2)(6) ring motifs generate a polymeric network.

SUBMITTER: Awan SA

PROVIDER: S-EPMC3089308 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κC,S:S)tetrakis[chloridocobalt(III)].

Awan Shafique Ahmad SA Tahir M Nawaz MN Muhammad Iram Khushi IK Ahmad Saeed S Tariq Muhammad Ilyas MI

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra-hedral geometry by one C, one Cl and two S atoms. The mol-ecules are stabilized by C-H⋯Cl hydrogen bonds. In the crystal, inter-molecular C-H⋯Cl and C-H⋯S hydrogen bonds with R(2) (2)(8), R(4) (2)(8) and R(2) (2)(6) ring motifs generate a polymeric network. ...[more]

PMID: 21754303

Similar Datasets

μ-Peroxido-bis-[acetonitrile-bis-(ethyl-enediamine)-cobalt(III)] tetrakis(per-chlorate).

Project description:The title compound, [Co(2)(O(2))(CH(3)CN)(2)(C(2)H(8)N(2))(4)](ClO(4))(4), consists of centrosymmetric binuclear cations and perchlorate anions. Two Co(III) atoms, which have a slightly distorted octa-hedral coordination, are connected through a peroxido bridge; the O-O distance is 1.476 (3) Å. Both acetonitrile ligands are situated in a trans position with respect to the O-O bridge. In the crystal, the complex cations are connected by N-H⋯O hydrogen bonds between ethyl-endiamine NH groups and O atoms from the perchlorate anions and peroxide O atoms.

| S-EPMC3011807 | biostudies-literature

Tetrakis(μ(3)-9-oxa-10-boraanthracen-10-olato)tetrakis[(diethyl ether)lithium].

Project description:The title compound, [Li(4)O(4)(C(12)H(8)BO)(4)(C(4)H(10)O)(4)], features a Li(4)O(4) cube. Each Li atom in the cube is additionally coordinated by a diethyl ether mol-ecule and each O atom in the cube carries a 9-oxa-10-boraanthracene residue. The crystal studied was a non-merohedral twin [twin law (-1 0 0 / 0 0 1 / 0 1 0); the contribution of the major twin component refined to 0.553 (3)] emulating apparent tetra-gonal symmetry, whereas the actual crystal system is just ortho-rhom-bic.

| S-EPMC3246952 | biostudies-literature

catena-Poly[[bis-(N-ethyl-ethylene-di-amine-κN,N')copper(II)]-μ-cyanido-κN:C-[dicyanido-κC-palladium(II)]-μ-cyanido-κC:N].

Project description:The title compound, [CuPd(CN)(4)(C(4)H(12)N(2))(2)](n), consists of one-dimensional chains. The Cu and Pd atoms are both located on centers of symmetry in an alternating array of [Cu(N-Eten)(2)](2+) (N-Eten = N-ethyl-ethylenediamine) and [Pd(CN)(4)](2-) units. The Pd-C distances of 1.991 (3) and 1.992 (3) Å are inter-mediate values compared with the analogous Ni(II) and Pt(II) complexes [Akitsu & Einaga (2007 ▶). Inorg. Chim. Acta, 360, 497-505]. Due to Jahn-Teller effects, the axial Cu-N bond distance of 2.548 (2) Å is noticeably longer than the equatorial distances [Cu-NH(2) = 2.007 (2) and Cu-NHC(2)H(5) = 2.050 (2) Å]. There are interchain hybrogen bonds, with N(-H)⋯N = 3.099(4) Å.

| S-EPMC2969003 | biostudies-literature

{μ-6,6'-Dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}methanol-μ-nitrato-dinitratocopper(II)europium(III).

Project description:In the title dinuclear salen-type complex, [CuEu(C(22)H(24)N(2)O(4))(NO(3))(3)(CH(3)OH)], the Cu(II) ion is five-coordinated to two imine N atoms and two phenolate O atoms and one O from the bridging nitrate group. The Eu(III) ion is ligated to three nitrate groups, four O atoms from the salen-type ligand and one methanol mol-ecule, leading to a distorted tenfold coordination for the rare earth cation. One of the three nitrate anions is disordered over two positions in a 0.66 (5):0.34 (5) ratio.

| S-EPMC3008985 | biostudies-literature

Poly[tetrakis(μ-1,1,1,3,3,3-hexafluoropropan-2-olato)iron(II)dipotassium].

Project description:The title compound, [K2Fe{OCH(CF3)2}4] n , was formed from the reaction of potassium hexa-fluoro-isopropoxide with iron(II) chloride in toluene. The Fe(II) atom has a highly distorted tetra-hedral coordination environment. All four of the non-equivalent hexa-fluoro-isoprop-oxy O atoms link the Fe(II) atoms to one of the K(+) atoms in an alternating chain of Fe-O-K-O fused four-membered rings, with K-Fe distances of 3.715 (2) and 3.717 (2) Å. This K(+) atom is also bridged to eight of the F atoms. The other K(+) atom is bonded to only two of the O atoms, but has seven short K⋯F contacts, one of which links the chains into a three-dimensional arrangement. Weak hydrogen bonding between the lone H atoms on the hexa-fluoro-isoprop-oxy groups and F atoms is also present. The crystal studied was refined as an inversion twin.

| S-EPMC3998246 | biostudies-literature

Di-μ-chlorido-bis-{[2-(morpholinometh-yl)phenyl-κC,N]palladium(II)}.

Project description:The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol-ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intra-molecular N→Pd coordination trans to a Pd-Cl bond. In the crystal structure, the dimeric structure is strengthened by inter-molecular C-H⋯Cl hydrogen bonds. C-H⋯C(phen-yl) inter-actions link the dimers into a columnar supra-molecular array along the a axis; the dimers are further connected by C-H⋯Ph inter-actions into a three-dimensional supra-molecular arrangement.

| S-EPMC2961971 | biostudies-literature

Tetrakis[μ-3-(3-pyridyl)acrylato-κO:O']bis{(1,10-phenanthroline-κN,N')[3-(3-pyridyl)acrylato-κO,O']europium(III)} pentahydrate.

Project description:The europium(III) ion in the title compound, [Eu(2)(C(8)H(6)NO(2))(6)(C(12)H(8)N(2))(2)]·5H(2)O, is coordinated by seven carboxyl-ate O atoms and two N atoms from one phenanthroline mol-ecule. The carboxyl-ate groups of 3-(3-pyrid-yl)acrylate link pairs of europium(III) ions, forming centrosymmetric dinuclear units, which further assemble into a sheet parallel to the (001) plane through hydrogen-bonding inter-actions involving the uncoordinated water mol-ecules. One water molecule is disordered.

| S-EPMC2915131 | biostudies-literature

Bis(μ-chloroacetato-κO:O')bis(chloro-acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl-tin(IV)].

Project description:The title tetra-nuclear complex mol-ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal-bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C-H⋯O hydrogen bonds. In the crystal, complex mol-ecules are linked into zigzag chains along [110] by C-H⋯O hydrogen bonds.

| S-EPMC3051761 | biostudies-literature

catena-Poly[[[diaqua-(nitrato-κO,O')(2,2':6',2''-terpyridine-κN,N',N'')neodymium(III)]-μ-cyanido-κN:C-[dicyanidoplatinum(II)]-μ-cyanido-κC:N] acetonitrile solvate 2,2':6',2''-terpyridine hemisolvate].

Project description:The title compound, {[NdPt(CN)(4)(NO(3))(C(15)H(11)N(3))(H(2)O)(2)]·CH(3)CN·0.5C(15)H(11)N(3)}(n), was isolated from solution as a one-dimensional coordination polymer. The Nd(3+) site in the structure has a ninefold coordination with a distorted tricapped trigonal-prismatic geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. Cis-bridging by the tetracyanidoplatinate anions links the Nd(3+) cations, forming the one-dimensional chains. Additionally, each Nd(3+) contains coordin-ation by two water mol-ecules, one tridentate 2,2':6',2''-terpyridine mol-ecule, and one bidentate nitrate anion. 2,2':6',2''-Terpyridine and acetonitrile solvent mol-ecules are incorporated between the chains, the former form π-stacking inter-actions (average inter-planar distance 3.33 Å) with terpyridine mol-ecules located in the chains. Relatively long Pt⋯Pt inter-actions [3.847 (1) Å] are observed in the structure. O-H⋯N and O-H⋯O hydrogen bonding interactions between the consituents consolidates the crystal packing.

| S-EPMC2969978 | biostudies-literature

Bis(1,4-diazo-niabi-cyclo-[2.2.2]octa-ne) di-μ-chlorido-bis-[tetra-chlorido-anti-monate(III)] dihydrate.

Project description:The title salt, (C6H14N2)2[Sb2Cl10]·2H2O, was obtained by slow evaporation of an acidic solution of 1,4-di-aza-bicyclo-[2.2.2]octane and SbCl3. The crystal structure consists of (C6H14N2)(2+) cations, [Sb2Cl10](4-) double octa-hedra and lattice water mol-ecules. All mol-ecular components are situated on special positions. The cation and the lattice water mol-ecule exhibit mirror symmetry, whereas the anion has site symmetry 2/m. The cations, anions and water mol-ecules are alternately arranged into columns along [010]. Individual columns are joined into layers extending along (001). Intra-layer N-H⋯O and inter-layer N-H⋯Cl hydrogen-bonding inter-actions lead to the formation of a three-dimensional network.

| S-EPMC3684890 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data